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Anissa Bendjeriou-Sedjerari

Anissa Bendjeriou-Sedjerari

King Abdullah University of Science and Technology, Saudi Arabia

Title: “Catalysis by Design”: From Conventional Solid State NMR Spectroscopy to the Dynamic Nuclear Polarization Surface Enhanced Spectroscopy (DNP-SENS) - The Success Story of Single Site Well-Defined Heterogeneous Catalysts

Biography

Biography: Anissa Bendjeriou-Sedjerari

Abstract

Heterogeneous catalysis is ubiquitous today and is central to solving many of the key problems facing chemistry including energy and environmental issues that contribute to a sustainable world. However, the main drawback is due to the multiplicity of active sites in terms of surface and bulk structure which makes it difficult to reflect the intrinsic efficiency of catalysts. The concept of “Catalysis by Design” requires the establishment of structure-activity relationship.[1] Surface Organometallic Chemistry (SOMC) thanks to its solid track record, provides a single-site strategy by creating well-defined surface organometallic fragments (SOMF) that are presumed to be part of the catalytic cycle. [1-3] To achieve this goal, the surface complexes need to be unambiguously characterized by advanced multi-dimensional solid-state NMR spectroscopy.[1-5] Recently, the sensitivity limitations encountered with the conventional solid state NMR spectroscopy have been overcome by the emergence of Dynamic Nuclear Polarization Surface Enhanced Spectroscopy (DNP-SENS) that requires the use of polarizing agent (radical nitroxide). [6-7] DNP-SENS can be now successfully applied to characterize highly sensitive SOMF in reasonable acquisition time. [8] By combining these essential and powerful spectroscopic tools, structure–activity relationships can be highlighted.